A Thermodynamic Study of the Charge Transfer Complexes of [60] Fullerene with Thiapodands
Journal Title: Journal of Chemistry and Applied Biochemistry - Year 2017, Vol 4, Issue 1
Abstract
Formation of charge-transfer complexes between thiapodands1-6 and [60]fullerene, C60, were studied in toluene solution using UV-Vis spectrophotometry. The stability constants and the thermodynamic data of the resulting 1:1 complexes were determined. For thiapodands with ester groups ending, the order of stability constants of [60]fullerene-podands, 1-3 is in the order 1>2>3 while for thiapodands with amide groups ending, the order of stability constants of [60] fullerene-podands, 4-6 is 6>5>4.
Authors and Affiliations
Shehadeh Mizyed
Keywords
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