CATALYTIC HYDROSILYLATION OF 5-METHYLHEXENE-5-YN-2-OL-1
Journal Title: Azerbaijan Chemical Journal - Year 2019, Vol 0, Issue 2
Abstract
The addition of trialkylsilanes to 5-methylhexene-5-yn-2-ol-1 in the presence of H2PtCl6.6H2O proceeds via a triple bond, but with an advantageous yield (80-90%) of the β-isomer (relatively oxygen atom). The reaction of organosilicon 1,4-diene alcohol with 1-chloro-2,3-epoxypropane, boric acid and acrylonitrile produced corresponding chlorohydrin, tris-borate and nitrile
Authors and Affiliations
A. M. Garamanov, N. Kh. Gusiev, D. G. Abdullaev, O. B. Abdiev, M. Sh. Gurbanov, S. A. Rzaeva
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