Functionalization of Carboxylated Multi-Walled Nanotubes with Stabilised Phosphorus Ylide
Journal Title: International journal of Advanced Biological and Biomedical Research - Year 2014, Vol 2, Issue 7
Abstract
In this paper, the chemical Functionalization of Carboxylate multi-walled carbon nanotubes by methyl (triphenyl phosphoranylidene) acetate have been investigated. Phosphorus Ylides are important compound in organic chemistry. At first, methyl (triphenyl phosphoranylidene) acetate, synthesized from salt metod in two steps: the formation of the phosphonium salt and the deprotonation of the latter to form the ylide. MWNT-Slide is obtained through MWNT-cocl with methyl (triphenyl phosphoranylidene) acetate, which is confirmed by FT-IR, SEM and elemental analysis. The functionalized MWNTs were dispersed very well in solvent of dimethylformamide (DMF), and the high stability of dispersed suspension could be maintained for more than 1 week without MWNT precipitation. These Functionalization have been chosen due to P=C and C=O active sites in MWNT-ylide for future application.
Authors and Affiliations
Elnaz Nassaghi| Department of chemistry, College of fundamental sciences, shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran, Javad Azizian| Department of chemistry, College of fundamental sciences , Science and Research Branch, Islamic Azad University, Tehran, Iran, Sajjad Sedaghat| Department of chemistry, College of fundamental sciences, shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran
Keywords
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