Kinetic resolution of racemic mixture of 2-butyryloxy-2-(ethoxy-P-phenylphosphinyl)acetic acid by fungi Penicillium oxalicum
Journal Title: CHEMIK nauka-technika-rynek - Year 2014, Vol 68, Issue 9
Abstract
The aim of the study was to resolve the racemic mixture of 2-butyryloxy-2-(ethoxy-P-phenylphosphinyl)acetic acid by kinetically controlled biotransformation with whole-cell biocatalyst – Penicillium oxalicum strain with confirmed lipolytic activity. Also effect of the vegetable oil addition on induction of fungal lipases synthesis and efficiency of the biotransformation process was examined. The use of inductors did not positively influenced the degree of substrate conversion, while significant differences were observed in the enantioselectivity of the reaction.
Authors and Affiliations
M. Serafin, E. Żymańczyk-Duda
Keywords
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