Nano-sized Mercury(II) Schiff Base Complexes: Synthesis, Characterization and Thermal Studies
Journal Title: Chemical Methodologies - Year 2020, Vol 4, Issue 1
Abstract
In this paper, nano-sized of two mercury(II) complexes with the general formula of HgLX2 (X=Br (1) and I (2)), L=N,N¢-bis{(paramethylamino)benzylidene}ethylenediamine have been prepared by ultrasonic bath assisted from the reaction of HgX2 and L in molar ratio 1:1 in methanol solution. The complexes were characterized by elemental analyses (CHN) and FT-IR spectroscopy, XRD and SEM. In addition, thermal stability of complexes was studied.
Authors and Affiliations
Aliakbar Dehno Khalaji
Effects of Freeze-drying and Freezing on Vitamins and Sugars of Mango Pulp (‘Apple’ Cultivar): A Preliminary Comparison of Methods for Improving Sample Storage
Mango (Mangifera indica L.) fruits are highly perishable ones whose important nutrients such as vitamins and sugars quickly decrease under storage. In this study, we compared two methods of fruit pulp storage; freezing a...
Evaluating Adsorption of Proline Amino Acid on the Surface of Fullerene (C60) and Carbon Nanocone by Density Functional Theory
Determination of proline is of great importance and investigating the interaction of this amino acid with nanostructures play a key role in the construction of novel appropriate sensors for proline measurement. In this r...
Metal-Organic Framework MIL-53(Fe) as a highly efficient reusable catalyst for the synthesis of 2-aryl-1H-benzimidazole
Metal-organic framework MIL-53(Fe) (MIL = materials of institute lavoisier) as a recyclable and heterogeneous catalyst efficiently catalyzed the synthesis of 2-aryl-1H-benzimidazole derivatives from o-phenylenediamine an...
Investigation of Adsorption of the Nitrosamine Molecule as a Carcinogen Agent on the AlN Nanotubes: A DFT Study
In this study, chemical reactivity of (4,0) and (5,0) AlN nanotubes by interaction with nitrosamine molecule as a carcinogen agent was investigated using the B3LYP/6-311++G (d) level of theory. The HOMO–LUMO gap, electro...
Eutectic Mixture Choline Chloride–Chloroacetic acid: a New and Efficient Catalyst for Synthesis of 3,4-Dihydropyrimidin-2-ones
Deep Eutectic Solvents (DES) with the properties of an ionic liquid can be formed between choline chloride and chloroacetic acid in a 1:1 molar ratio. In this paper, we discuss our success in synthesizing dihydropyrimidi...