OXIDATIVE DEHYDROGENATION OF CYCLOHEXANE OVER MODIFIED ZEOLITE CATALYST
Journal Title: Azerbaijan Chemical Journal - Year 2016, Vol 0, Issue 4
Abstract
It has been investigated the catalytic activities of modified zeolites in the reaction of oxidative dehydrogenation of cyclohexane. It has been determined that the CuZnCoCr-clinoptilolite (Cu2+-0.5%; Zn2+-0.2%; Co2+--0.1%; Cr3+-0.1%) polimetale zeolite catalyst shows higest activity in this reaction. The kinetic scheme of mehanism of reaction has been suggested and kinetic model of this process has been developed. It has been calculated the kinetic parametres of kinetic model
Authors and Affiliations
A. M. Aliyev, Z. A. Shabanova, U. M. Najaf-Quliyev, A. I. Karimov
Keywords
Related Articles
- EP ID EP439104
- DOI -
- Views 141
- Downloads 0
ELECTROCHEMICAL BEHAVIOR OF SULPHITE IONS IN THE TARTARIC ELECTROLYTE
The paper is devoted to electrochemical reduction of sulfite ions from tartaric acid electrolytes. Kinetics and mechanism of the process, the effect of some factors on electroreduction process of sulphite ions have been...
THE HYDROSILYLATION OF 3-(HEXEN-5-IN-2-ILOXY) PROPIONITRILE
The addition reaction of triorganosilanes to 3-(hexen-5-in-2-iloxy) propionitryle in the presence of acetylacetonate dicarbonyl rhodium catalyst proceeds on triple bonds in two directions obtaining of β(52–65%)- and γ(3...
SPECTROPHOTOMETRIC DETERMINATION OF COPPER WITH N,N-bis-(3-PHENYLAZO-2,4-PENTANEDIONE)ETHYLЕNE DIIMINE IN PRESENCE AND ABSENCE OF AMINES
For determining the method of photometric used the reaction of Cu with N,N-bis-(3-phenilazopentadion-2,4)ethylene diimine with 1,10-phenantrolin, 2,2’-dipiridil and ethylene diamine. The complex product which is getting...
SPECTROPHOTOMETRIC DETERMINATION OF IRON(III) WITH 3-((2-HYDROXYPHENYL)DIAZENYL)PENTADIONE-2,4 AND DIANTIPYRYLMETHANE
The complex formation of iron(III) with 3-((2-hydroxyphenyl)diazenyl)pentadione-2,4 and diantipyrylmethane was investigated by spectrophotometric method and highly selective method of determination of its microamounts in...
THE SYNTHESIS OF NEW MONOOXYGENASE BIOMIMETIC CATALYSTS AND OXIDATION IN THE THEIR PRESENCE OF HYDROCARBONS BY HYDROGEN PEROXIDE TO CHEMICALLY IMPORTANT COMPOUNDS
Heterogeneous ironporphyrin-containing biomimetic catalysts were investigated for their selectivity in relation of determined compound in the cyclohexane gas-phase oxidation process and mixture of the latter with its der...