OXIDATIVE REACTION OF SUCROSE WITH POTASSIUM PERMANGANATE IN AQUEOUS ACEDIC MEDIUM – A KINETIC AND MECHANISTIC APPROACH
Journal Title: Indian Journal of Scientific Research - Year 2017, Vol 8, Issue 1
Abstract
Oxidative reaction of sucrose by potassium permanganate in aqueous acidic medium has been investigated spectrophotometrically. Systronic visible Spectrophotometer -105 was used for data collection.. The determination of thermodynamic parameters has been determined with varying the temperature from 30°C - 50°C and keeping constant other ingradients. First order rate of reaction enhanced with increasing the temperature. The enthalpy of activation (∆H), free energy of activation (∆G) were recorded with positive value, while entropy of activation (∆S) with highly negative value indicates the formation of solvated molecular complex in rate determining step. Rate law of the oxidation reaction and mechanism were suggested for current research work.
Authors and Affiliations
YUGENDRA KUMAR SONI
Keywords
Related Articles
- EP ID EP370645
- DOI -
- Views 59
- Downloads 0
A CASE OFAN UNHEARD TRIO OF COMPLICATIONS OF CHRONIC DUODENAL ULCER FROM GASTRIC OUTLET OBSTRUCTION, CHOLEDOCHODUODENAL FISTULAAND COMMON BILE DUCT STRICTURE
Commonly encountered complications of duodenal ulcer [DU] are bleeding and perforation, while gastric outlet obstruction [GOO] is uncommon. Penetrating duodenal ulcer leading to Choledochoduodenal Fistula [CDF] or Common...
TRITERPENOIDS FROM POGOSTEMON BENGHALENSE
Anew natural triterpenoid Lanost-8(9),25-dien-3-one has been isolated from aerial parts of Pogostemon benghalense in addition to !-Sitosterol andLupeol acetate.
MICROBIAL DEGRADATION OF 4-CHLOROBENZOIC ACID BY Pseudomonas putida STRAIN PS–I
Pseudomonas putida strain PS- I, a 4-chlorobenzoic acid degrading bacteria was isolated from soil. This bacterium could degrade 13 mM of 4-chlorobenzoic acid rapidly with stiochiometric formation of chloride ion. Metabol...
SOLVENT EFFECT IN NMR SPECTRA OF DB30C10 , DB18C6 AND B18C6 CROWN ETHER MOLECULES
NMR spectra of various Crown compounds(DB30C10) , DB18C6 and B18C6) determined using different solvent to know what is the solvent impact on Coupling constants. The present study is Highly valuable to know...
MANAGEMENT OF NON-SYNDROMIC MULTIPLE IMPACTED SUPERNUMERARY TEETH: A RARE CASE REPORT
Supernumerary teeth or hyperdontia is additional tooth, teeth or tooth like structures that either have erupted or remain unerupted in addition to the 20 deciduous and 32 permanent teeth.Supernumerary teeth may erupt nor...