POTENTIOMETRIC DETERMINATION OF STABILITY CONSTANTS OF COMPLEXES OF RARE EARTH ELEMENTS WITH ARYLHYDRASONS OF BENZOYLACETONE
Journal Title: Azerbaijan Chemical Journal - Year 2018, Vol 0, Issue 4
Abstract
The stability constants of the complexes of rare earth elements – La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu with arylhydrazones of benzoylacetone have been determined by the method of potentiometric titration, which change in the following sequence: Lu > Yb > Tm > Er > Ho > Dy > Tb > Gd > Eu > Sm > Nd > Pr > Ce > La. The stability of the complexes depends on the electron-donor and electron-acceptor character of the functional groups included in the ligands: –Cl>–SO3H>–NO2
Authors and Affiliations
F. E. Huseynov, A. M. Maharramov, K. T. Mahmudov
Keywords
Related Articles
- EP ID EP493281
- DOI 10.32737/0005-2531-2018-4-13-16
- Views 139
- Downloads 0
MECHANISM AND MATHEMATICAL MODEL OF THE PROCESS OF GRANULATING THE POWDER-LIKE MATERIALS IN THE DRUM DEVICES
On the grounds of the mechanism and kinetic regularities of granule formation of powder-like materials the mathematical odel of the process in the drum devices has been constructed. It has been established that granulat...
USING NANODEMULSIFIERS FOR DEMULSIFICATION OF THE OIL EMULSIONS IS ONE OF PRIORITY DIRECTIONS OF MODERN OIL-FIELD CHEMISTRY
The article presents the results of laboratory and experiment-industrial tests of compositions of nanodemulsifiers IKHLAS-1–42 (based on high- and low-molecular surfactants) on the oil fields "Zhetybai" and "Zhanaozen...
THE SYNTHESIS OF NEW MONOOXYGENASE BIOMIMETIC CATALYSTS AND OXIDATION IN THE THEIR PRESENCE OF HYDROCARBONS BY HYDROGEN PEROXIDE TO CHEMICALLY IMPORTANT COMPOUNDS
Heterogeneous ironporphyrin-containing biomimetic catalysts were investigated for their selectivity in relation of determined compound in the cyclohexane gas-phase oxidation process and mixture of the latter with its der...
SYNTHESIS OF SILVER NANOPARTICLES IN THE PRESENCE OF NATURAL AND SYNTHETIC POLYMERS AND THE INVESTIGATION OF THEIR MORPHOLOGICAL STRUCTURES
The results of works (including also the authors of the given review) in a field of obtaining the stable nanoparticles of silver and study of the mechanism of their f0rmation at reducing Ag ions in aqueous solutions in t...
INFLUENCE OF OZONOLYSIS ON GROUP HYDROCARBON AND ELEMENTARY COMPOSITION OF VACUUM GAS OIL
Influence of ozonolysis on group and elementary composition of vacuum gas oil has been studied. It was determined that during ozonolysis the most change of group hydrocarbon composition has been noticed: difference in co...