Research progresses of CO oxidation catalysts with superior SO_2 resistance
Journal Title: Energy Environmental Protection - Year 2024, Vol 38, Issue 4
Abstract
Carbon monoxide (CO) is a common air pollutant in industrial flue gas and motor vehicle exhaust, and its excessive emissions pose a serious threat to human health. Currently, catalytic oxidation technology is widely used for CO emission control. However, sulfur dioxide (SO_2), which is prevalent in industrial flue gas and motor vehicle exhaust, can cause irreversible poisoning of CO oxidation catalysts, resulting in their severe deactivation. Therefore, improving the SO_2 resistance performance of CO oxidation catalysts has become a research hotspot in the field of environmental catalysis. This review summarizes the SO_2 poisoning mechanism on CO oxidation catalysts, categorizes the methods of characterizing sulfur species on the catalyst surface, and discusses effective strategies to enhance the SO_2 resistance performance of various CO oxidation catalysts. This review will contribute to the understanding of the adsorption and transformation processes of SO_2 on the catalyst surface, revealing the mechanism of the interaction between SO_2 and catalysts, and providing significant references for the design and synthesis of CO oxidation catalysts with superior SO_2 resistance performance.
Authors and Affiliations
TAN Wei|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, MU Yibo|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, ZHANG Bifeng|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, CAI Yandi|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, JI Xiaoyu|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, YANG Jiawei|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, JIANG Nan|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China, GUO Kai|State Key Laboratory of Green Chemical Engineering andIndustrial Catalysis, Sinopec Shanghai Research Institute of Petrochemical Technology Co., Ltd., Shanghai 201208, China, LIU Annai*|Sinopec Catalyst Co., Ltd., Sinopec Group, Beijing 100176, China, DONG Lin*|State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210023, China, Jiangsu Key Laboratory of Vehicle Emissions Control, School of Environment, Nanjing University, Nanjing 210023, China
Advances in value-added depolymerization by catalytic fast pyrolysis of lignin
Lignin is a complex three-dimensional amorphous natural aromatic polymer with great potential to be converted into biofuels as an alternative to traditional fossil fuels. Pyrolysis technology has been proven to be as an...
Experimental study on the extraction of aluminum and iron from coal gangue by thermal activation and acid leaching method
A massive amount of coal gangue (an accompanying solid waste) is produced during coal mining and washing processes, leading not only to the wastage of land resources but also to environmental impacts. Due to the abundant...
Experimental study on VOCs adsorption by Zr-MOFs synthesized with different ligands
Zirconium-based MOFs adsorbent materials with different ligands, including: UIO - 66, UIO-66-NH_2, UIO-66-NDC and UIO-67 were hydrothermally synthesized using terephthalic acid as the base ligand and functionalized funct...
Risks and coping strategies for energy low-carbon transitions: Research based on the new concept of energy security
Energy low-carbon transitions have become a crucial approach for countries around the world to cope with climate crisis and promote sustainable development. However, most of the existing studies have analyzed the risks a...
Effect of Ga, Zn modified ZSM-5 catalysts on the biomass catalytic pyrolysis for MAHs production
In order to solve the existing problem of bio-oil, which contains complex compounds and has a high oxygen content, research was conducted on biomass catalytic pyrolysis and reaction mechanisms to enhance the quality of b...