Synthesis, Crystal Structure and Vibrational Properties of bis (N-benzylmethylammonium) Pentachlorobismuthate (III)
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 8, Issue 2
Abstract
The [C8H12N]2 BiCl5 compound crystallised in the triclinic system with space group  P-1  with a = 9,833(4),                     b = 10,044(7), c = 12,225(7) Ã…, a= 78.82(4), β = 75,42(4), g= 76.89°(5)  and Z = 2. The average density value, Ïx = 1.518 g.cm-3 is in agreement with the calculated one, Ïx = 1.494 g.cm-3. The atomic arrangement can be described as an alternation of organic and inorganic layers. The anionic layer is built up of octahedral [Bi2Cl10]-4. The organic layers are arranged in sandwich between the anionic ones. The crystal packing is governed by means of the ionic N–H---Cl hydrogen bonds, forming a three dimensional network. The nature of the distortion of the inorganic polyhedra has been studied and can be attributed to the stereo activity of the Bi(III) lone electron pair. The infrared and Raman spectra was recorded in the 4000–400 cm-1 frequency region.
Authors and Affiliations
Hiba Khili, Najla Chaari, Mohamed Fliyou, Slaheddine Chaabouni
Keywords
Related Articles
- EP ID EP652633
- DOI 10.24297/jac.v8i2.4038
- Views 155
- Downloads 0
Selective C-methylation of phenol with methanol over transition metals modified mesoporous ceria catalysts
The demand for selective catalysts with larger molecular dimensions led to the discovery of mesoporous catalytic materials. We report herein the development of an environmentally friendly process for C-methylation of phe...
Green synthesis of Novel Schiff bases derived from 2, 6 diamino pyridine – Characterization and Biological activity
Present work produces an excellent green route for the synthesis of Schiff bases derived from 2, 6 diamino pyridine, by using lemon juice as the catalyst. This method is experimentally simple, quick, clean and high yield...
Chemical and Electrochemical studies on the corrosion of mild-steel, copper and zinc in 0. 5 M H2SO4 solution in presence of Azithromycin as effective corrosion inhibitor
Azithromycin has been tested as inhibitor for steel, copper and zinc corrosion in 0.5 M H2SO4 was studied using potentiodynamic polarization and electrochemical impedance spectroscopy. The results showed that the inhib...
Dinuclear UO2(VI), Th(IV), ZrO(IV) and VO(IV) complexes based on some Schiff-base ligands: Synthesis and structural elucidation
A series of homo binuclear complexs of the type [M2(L/L’)(NO3)n(H2O)2], [where M=UO22+, Th4+, ZrO2+] and [(VO)2(L/L’)(SO4)(H2O)], L= 4, 17-di(o-hydroxyphenyl)-5,6,9,12,15,16-hexaaza-7,8,13,14-tetraphenyl heptadec-4,...
THE INHIBITION AND ADSORPTION PROPERTIES OF DTPMP TSC ON STAINLESS STEEL IN ACIDIC MEDIUM
The inhibition effect of diethylenetriamine penta(methylene phosphonic acid) (DTPMP) and Trisodium Citrate (TSC) on thecorrosion behavior of stainless steel in 0.5 M H2SO4 solution was investigated by using weight loss m...