SYNTHESIS OF NEW AMINOMETHYL AND ORGANYLSULPHIDE DERIVATIVES OF PIPERIDINO-2-HYDROXYPROPANETHIOL-3
Journal Title: Azerbaijan Chemical Journal - Year 2018, Vol 0, Issue 4
Abstract
At interaction of hydrogen sulphide with piperidino-2,3-epoxyprorane there is formed piperidino-2- hydroxypropanthiol-3. The latter reacts by Mannich with formaldehyde and secondary aliphatic and heterocyclic amines, as well with organic halogenide, forming respectively aminomethyl and organyl-sulphide derivatives of piperidino-2-hydroxypropanethiol-3. Composition and structure of synthesized compounds are confirmed by elemental analysis and method NMR
Authors and Affiliations
V. M. Farzaliyev, Sh. R. Aliyev, R. F. Mammadova, R. M. Babai, Q. M. Quliyeva
Keywords
Related Articles
- EP ID EP493251
- DOI 10.32737/0005-2531-2018-4-6-12
- Views 135
- Downloads 0
THE REACTIONS OF α-METHOXYAMIDES WITH MALONONITRILE IN THE PRESENCE OF TiCl4 AS A CATALYST
By using Asinger reaction 2,5-dihydro-1,3-thiazoles obtained in high yields. Treating these heterocyclic imines with acid chlorides followed by methanolysis of formed N-acyliminium chlorides led to a large number of α-me...
ON RESEARCH RESULTS OF INTERRELATION PROPERTY–STRUCTURE FOR n-ALIPHATIC ALCOHOLS
The research results of interrelation property–structure for n-aliphatic alcohols (C1–C10, in some cases C1–C18) with some physical (density, boiling temperature), rheological (freezing point, dynamic viscosity) and coll...
THE ACTIVITY OF THE ZINC–COBALT OXIDE SYSTEM IN THE REACTION OF ETHANOL STEAM REFORMING
Reaction of ethanol steam reforming to hydrogen over binary zinc–cobalt oxide catalysts of different compositions has been studied. It is found that at low temperatures the reaction products are acetaldehyde and acetone,...
NITROGEN FIXATION AT CONJUGATED OXIDATION
Using the new principle of nitrogen oxidation by hydroperox¬ide has helped in discovering a new method of nitrogen fixation, mainly shaped as N2O, other oxides with low admixtures or nitrogen-containing acids under condi...
THREE-COMPONENT SYNTHESIS ON THE BASIS OF VARIOUS BENZYLIDENEMALONONITRILES
There has been revealed the formation of substituted imino- and imidazopyridines by the one-pot, catalyst free three-component reaction of some benzylidenemalononitriles with malononitrile and various amines. Struc¬tu¬re...