Synthesis Of Photoconducting Polycarbonate Of Chloroformic ester of 3,6-bis-(hydroxyl methyl)-N-ethyl Carbazole With Bisphenol-A.
Journal Title: IOSR Journal of Applied Chemistry (IOSR-JAC) - Year 2018, Vol 11, Issue 2
Abstract
N-ethyl carbazole was synthesized by treating Carbazole with ethyl iodide in presence of Sodium hydride in Solvent medium of DMF. N-ethyl-3, 6-diformyl Carbazole was synthesized by reacting N-ethyl carbazole with high excess of POCl3 and DMF mixture. N-ethyl-3,6-bis(hydroxymethyl) carbazole was synthesized by treating N-ethyl-3,6-diformyl Carbazole with NaBH4 and NaOH mixture.Chloroformic ester of N-ethyl-3,6-bis(hydroxyl methyl) carbazole was prepared by treating N-ethyl-3,6-bis(hydroxymethyl) carbazole with phosgene in the solvent medium of toluene. Lastly the polymer was synthesized by the polycondensation reaction of chloroformic ester of N-ethyl-3,6-bis(hydroxyl methyl) Carbazole with Bisphenol-A in the solvent medium of toluene and pyridine. All the monomer and polymer was characterized by IR,UV and NMR spectroscopy.
Authors and Affiliations
Dipak Kumar Mukhopadhyay
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