Synthesis, structure and characterization of a new cadmium(II) iodide containing a tetradentate tripodal amine
Journal Title: JOURNAL OF ADVANCES IN CHEMISTRY - Year 2014, Vol 10, Issue 5
Abstract
A cadmium(II) iodide compound of the [Cd(L)I]I series, with L = tris(2-aminoethyl)amine, is synthesized and characterized. X-ray structural study shows that the title compound has a slightly distorted trigonal bipyramidal environment where the CdN4I chromophore is bounded by N atoms of L and one iodide. In the structural arrangement, the [Cd(L)I]+ cationic complexes are interconnected via N-H···I hydrogen bonds generated by the uncoordinated I iodide anions to form layers parallel to the (a, c) plane. The 13C CP-MAS NMR spectrum is discussed and the vibrational absorption bands were identified by infrared spectroscopy and DFT calculations.
Authors and Affiliations
Kamel Kaabi, Valeria Ferretti, Frederic Lefebvre, Cherif Ben Nasr
Keywords
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- EP ID EP652760
- DOI 10.24297/jac.v10i5.890
- Views 133
- Downloads 0
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