Use of Hydrazine Carboxamide-2-[(2-Hydroxy-1- Naphthalenyl) Methylene] as an Analytical Reagent for the Extractive Spectrophotometric Determination of U(Vi)
Journal Title: Journal of Pharmaceutical Research International - Year 2014, Vol 4, Issue 14
Abstract
Extraction and spectrophotometric determination of Uranium (VI) was carried out using Hydrazine Carboxamide-2-[(2-Hydroxy-1-Naphthalenyl) Methylene] as an analytical reagent. A reddish brown coloured complex is formed at pH 9.2 between U(VI):HCHNM which is extracted in n-butanol. An intense peak for the complex was observed at 385nm, well separated from that of ligand. Beer’s law is obeyed over the range of 2 to20 ppm. Composition of M:L in the complex was ascertained by Job’s method, mole ratio method and slope ratio method and found to be 1:2. Extraction and spectrophotometric determination of U(VI) was carried out using Hydrazine Carboxamide-2-[(2-Hydroxy-1-Naphthalenyl) Methylene] as an analytical reagent. A reddish brown coloured complex is formed at pH 9.2 between U(VI):HCHNM which is extracted in n-butanol. An intence peak for the complex was observed at 385nm, well separated from that of ligand. Beer’s law is obeyed over the range of 2 to 20 ppm. Composition of M:L in the complex was ascertained by Job’s method, mole ratio method and slope ratio method and found to be 1:2. Diverse ion effect was studied for various ions and the proposed method was found to be highly selective for the trace concentration of U(VI). Molar absorptivity and Sandell sensitivity values calculated are 0.1566 x104L mol-1cm-1 and 0.0585g/cm2 respectively. Proposed method has been successfully applied to analyse synthetic samples and the results were found to be in good agreement with standard gravimetric methods.
Authors and Affiliations
Ratnamala P. Sonawane
Keywords
Related Articles
- EP ID EP344694
- DOI 10.9734/BJPR/2014/7614
- Views 103
- Downloads 0
Effect of Andrographis serpyllifolia Leaves Extract on Experimentally Induced Typhoid Using Salmonella Typhi
Aims: The aim of the study was to evaluate the effect of the standardized ethanolic extract of Andrographis serpyllifolia leaves on experimentally induced typhoid. Study Design: Single dose of 1 ml Salmonella Typhi (106...
The Protective Role of Extract of Allium cepa Linn. (Liliaceae) (Red Onion) Bulb in Artesunate-induced Testicular Damage in Male Wistar Rats
Aim: Allium cepa is consumed fresh or cooked in Nigeria and used as herb in ethno-medicinal practice against many ailments. The aqueous extract is used in the management of prostrate inflammation, alleviation of low sper...
Public Knowledge and Awareness about Gout: A Cross-sectional Study in Qatar
Background: The prevalence of hyperuricemia and gout had shown an increasing trend all over the world including in developing countries. The patients may receive very little education on the dietary and lifestyle factors...
Clinical Outcome Evaluation of Glycaemic Control in a Metformin-based Therapy of Type 2 Diabetes Mellitus Patients Managed Under Ambulatory Care Settings
Background: Short term clinical outcomes evaluation of glycaemic goals or its control are desirable to monitor response to therapy in individual patients and to identify compliance or other problem areas. Aim and Objecti...
Adsorption – Desorption and Theoretical Study of Propranolol Hydrochloride Drug on Chitosan and Cellulose Acetate Surfaces
The research is concerned with the study of adsorption of propranolol hydrochloride drug on the surface of chitosan and cellulose acetate polymers. Adsorption isotherms of propranolol hydrochloride on the two surfaces us...