Use of Hydrazine Carboxamide-2-[(2-Hydroxy-1- Naphthalenyl) Methylene] as an Analytical Reagent for the Extractive Spectrophotometric Determination of U(Vi)
Journal Title: Journal of Pharmaceutical Research International - Year 2014, Vol 4, Issue 14
Abstract
Extraction and spectrophotometric determination of Uranium (VI) was carried out using Hydrazine Carboxamide-2-[(2-Hydroxy-1-Naphthalenyl) Methylene] as an analytical reagent. A reddish brown coloured complex is formed at pH 9.2 between U(VI):HCHNM which is extracted in n-butanol. An intense peak for the complex was observed at 385nm, well separated from that of ligand. Beer’s law is obeyed over the range of 2 to20 ppm. Composition of M:L in the complex was ascertained by Job’s method, mole ratio method and slope ratio method and found to be 1:2. Extraction and spectrophotometric determination of U(VI) was carried out using Hydrazine Carboxamide-2-[(2-Hydroxy-1-Naphthalenyl) Methylene] as an analytical reagent. A reddish brown coloured complex is formed at pH 9.2 between U(VI):HCHNM which is extracted in n-butanol. An intence peak for the complex was observed at 385nm, well separated from that of ligand. Beer’s law is obeyed over the range of 2 to 20 ppm. Composition of M:L in the complex was ascertained by Job’s method, mole ratio method and slope ratio method and found to be 1:2. Diverse ion effect was studied for various ions and the proposed method was found to be highly selective for the trace concentration of U(VI). Molar absorptivity and Sandell sensitivity values calculated are 0.1566 x104L mol-1cm-1 and 0.0585g/cm2 respectively. Proposed method has been successfully applied to analyse synthetic samples and the results were found to be in good agreement with standard gravimetric methods.
Authors and Affiliations
Ratnamala P. Sonawane
Keywords
Related Articles
- EP ID EP344694
- DOI 10.9734/BJPR/2014/7614
- Views 97
- Downloads 0
Thermo-TRP Channels in Pain Sensation
Important conceptual changes concerning human thermoregulation have revealed in the last decade. Recent investigations in central and peripheral thermosensitivity have emphasized the importance of temperature-activated t...
Preliminary Phytochemical Screening and In vitro Antioxidant Activity of Methanolic Extract of Tropaeolum majus L. Seed
Objective: To investigate the preliminary phytochemical screening and in vitro antioxidant activity of methanol extract of Tropaeolum majus L. (T. majus) seeds. Methods: Phytochemical screening was performed by using st...
Investigation of Enzymes Binding to “Voglibose- an Antidiabetic Drug” and the Choice of Enzyme to be Used for Biosensing
Aims: This paper mentions of the investigation of the enzymes binding to Voglibose and the choice of the enzyme which is suitable for drug enzyme interaction as used in biosensing. Voglibose is an antidiabetic drug which...
A Pilot Study to Evaluation of the Level of Knowledge and Quality of Water Used in Drug Reconstitution among Community Pharmacist in Palestine
Background: Water is widely used as diluents because of its ability to dissolve, absorb, or suspend many different compounds including reconstituted drugs. The quality of water used is important as it may include contami...
Evaluation of Antibacterial Activity of Bryopsis pennata and Chaetomorpha antennina against Multidrug Resistant Morganella morganii and Salmonella species Isolated from Healthy Individuals
The problem of antibiotic resistance is fast becoming a pandemic which has necessitated the need for new drugs discovery. This study was carried out to screen two green algal species- Bryopsis pennata and Chaetomorpha an...