Growth and optical properties of Er3+-doped BaGd2(MoO4)4 crystal
Journal Title: CHEMIK nauka-technika-rynek - Year 2013, Vol 67, Issue 9
Abstract
A 1 at% Er3+ doped BaGd2(MoO4)4 single crystal was grown by the Czochralski method. Details on the preparation and growth procedures were discussed. The crystal has a perfect (010) cleavage plane, and the cleavage character makes the crystal suitable as a gain medium for microchip lasers. The absorption spectrum in the visible and near-infrared (NIR) regions was measured at room temperature. There are several strong absorption peaks in the range from 380 to 1600 nm. The fluorescence spectrum excited by a Xenon lamp was also measured. A strong NIR emission peak located at 1536 nm was observed. The fluorescence lifetimes of 4I13/2 and 4I11/2 determined by a fit to a single exponential are around 5.85 ms and 112.62 μs, respectively. The specific heat of Er3+:BaGd2(MoO4)4 at 25°C is 0.471 J g-1 K-1. Using the measured spectra, the optical parameters were calculated using the J–O theory.
Authors and Affiliations
Shujuan Han, Jiyang Wang, Huaijin Zhang, Shilie Pan, Honghao Xv, Yicheng Wang, Chuanying Shen
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